Octopus-inspired flocculant for oily wastewater decontamination: Hydrophilic-hydrophobic convertibility and auto-separation characters

• Published in: Journal of hazardous materials Vol. 480; p. 136396
• Main Authors: Chen, Wei, Zhao, Zhihan, Du, Yuhan, Ouyang, Shuohao, Lin, Mengyi, Li, Fengya, Tang, Hanwei, Luo, Hongbing, Zhang, Ke, Zheng, Huaili
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05-12-2024
• Subjects: Auto-separation; Flocculation; Hydrophilic-hydrophobic transition; Mimic octopus; Oily wastewater; Auto-separation; Mimic octopus; Flocculation; Oily wastewater; Hydrophilic-hydrophobic transition
• ISSN: 0304-3894; 1873-3336; 1873-3336
• DOI: 10.1016/j.jhazmat.2024.136396

Unilateral hydrophobic flocculant and unsatisfactory floc separation constrained the efficacious purification of oil-containing wastewater. Illumined by the hunting behavior of mimic octopus, a biomimetic flocculant (CNSDA) with temperature-sensitive chains (color pouch) and hollow silica cores (mantle) was manufactured to derive hydrophilic-hydrophobic convertibility and auto-separation capabilities. Physical-chemical information of CNSDA was elucidated through characterization analysis. The flocculation behaviors of temperature-sensitive chains and hollow silica cores were evaluated by flocculation experiments. Results indicated that the configuration of CNSDA molecular chains varied from extension to constriction and revealed hydrophobicity as the temperature crossed 29.6 ℃. Compared with 20 ℃, the flocculation efficiencies rocketed at 40 ℃ by CNSDA, and excess flocculants were adsorbed by as-formed flocs through nonpolar interactions (the residual was low to 2.27 % at 160 mg/L). Concomitantly, the contracted molecular chains were contributed to generating dense flocs with low moisture content that flocked into large ones and expedited the solid-liquid separation process (60 % shorter than cationic polyacrylamide) with the auxiliary of low-density cores. The hydrophobic adsorption mechanism actuated by temperature-sensitive character was the decisive factor for high-efficiency flocculation. This study can provide meaningful references for the conception and exploitation of oily wastewater disposal agents.
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•Mimic octopus heuristic flocculant was manufactured for emulsified oil removal.•The hydrophobicity conversion of CNSDA enhanced hydrophobic matter captures.•Hydrophobic flocculant was conducive to the polymer residual decrease.•Hollow silica cores inside CNSDA accelerated the oil floc separation.