Electronic Tuning of Nickel-Based Bis(dicarbollide) Redox Shuttles in Dye-Sensitized Solar Cells

Redox nach Belieben: Die Synthese einer Reihe neuer borfunktionalisierter NiIII/NiIV‐Bis(dicarbollid)‐Cluster führt zu einer Familie von robusten und justierbaren Redox‐Shuttles. Dies bietet eine Möglichkeit zur gezielten Steuerung der Redoxeigenschaften farbstoffsensibilisierter Solarzellen, was in...

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Bibliographic Details
Published in:	Angewandte Chemie Vol. 122; no. 31; pp. 5467 - 5471
Main Authors:	Spokoyny, Alexander M., Li, Tina C., Farha, Omar K., Machan, Charles W., She, Chunxing, Stern, Charlotte L., Marks, Tobin J., Hupp, Joseph T., Mirkin, Chad A.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 19-07-2010 WILEY‐VCH Verlag
Subjects:	Bis(dicarbollid) Carborane Farbstoffsensibilisierte Solarzellen Redox-Shuttles Solarzellen
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Summary:	Redox nach Belieben: Die Synthese einer Reihe neuer borfunktionalisierter NiIII/NiIV‐Bis(dicarbollid)‐Cluster führt zu einer Familie von robusten und justierbaren Redox‐Shuttles. Dies bietet eine Möglichkeit zur gezielten Steuerung der Redoxeigenschaften farbstoffsensibilisierter Solarzellen, was in außergewöhnlich hohen Leerlaufspannungen resultierte.
Bibliography:	J.T.H. and T.J.M. gratefully acknowledge the support of BP Solar. T.J.M. also acknowledges the support of the Energy Frontier Research Center (DE-SC0001059) at the ANSER Center of Northwestern University. J.T.H. also thanks the U.S. DOE (Grant No. DE-FG02-87ER13808) for funding. C.A.M. acknowledges the DOE Office (Award No. DE-SC0000989) for support via the NU Non-equilibrium Energy Research Center. C.A.M. is also grateful for support from the U.S. ARO. U.S. DOE - No. DE-FG02-87ER13808 ark:/67375/WNG-7QZV50WZ-4 Energy Frontier Research Center - No. DE-SC0001059 ArticleID:ANGE201002181 DOE Office - No. DE-SC0000989 istex:8380EF8957803E2F48FB2F77722C64979CFFC30D BP Solar ANSER Center of Northwestern University These authors contributed equally to this work. J.T.H. and T.J.M. gratefully acknowledge the support of BP Solar. T.J.M. also acknowledges the support of the Energy Frontier Research Center (DE‐SC0001059) at the ANSER Center of Northwestern University. J.T.H. also thanks the U.S. DOE (Grant No. DE‐FG02‐87ER13808) for funding. C.A.M. acknowledges the DOE Office (Award No. DE‐SC0000989) for support via the NU Non‐equilibrium Energy Research Center. C.A.M. is also grateful for support from the U.S. ARO.
ISSN:	0044-8249 1521-3757
DOI:	10.1002/ange.201002181