Study on ablation behavior of ZrB2-SiC coating based on the high thermal conductivity substrate

• Published in: Journal of the European Ceramic Society Vol. 45; no. 2; p. 116918
• Main Authors: Zhang, Ruoxi, Zhou, Zhaofan, Shen, Qingliang, Song, Qiang, Li, Wei, Li, Hejun
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-02-2025
• Subjects: Ablation performance; High thermal conductivity substrate; Thermal shock performance; ZrB2-SiC coating; High thermal conductivity substrate; ZrB2-SiC coating; Ablation performance; Thermal shock performance
• ISSN: 0955-2219
• DOI: 10.1016/j.jeurceramsoc.2024.116918

The ZrB2-SiC coatings were prepared on SiC-coated 3D C/C composites with different substrates by supersonic atmospheric plasma spraying. Ablation tests of 80 s and 20×4 s were carried out in an oxyacetylene flame with a heat flux of 2.38 MW/m2 to evaluate the ablation resistance and thermal shock resistance of the ZrB2-SiC coating. Results show that the substrate of the HTC-XZZ specimen provides long-distance heat transfer channels, leading to a reduction of 174 °C and 237 ℃ in the surface temperature of the coating, which weakens the SiO2 consumption. Combined with the pinning stability of the sawtooth SiC inner layer on oxide film, ZrSiO4 is formed, which improves the compactness of the coating and effectively prevents oxygen diffusion, has good structural stability, and exhibits excellent ablation resistance and thermal shock resistance. This new thermal structure coating shows great application prospects in the field of thermal protection of materials.