Sorption of polynuclear aromatic hydrocarbons by sediments and soils

The sorption of pyrene, 3-methylcholanthrene, 7,12-dimethylbenz(A)anthracene, and dibenzanthracene on 14 soil and sediment samples exhibiting a wide range of physicochemical properties was studied. The equilibrium Freundlich constants and linear partition coefficients for each compound were highly c...

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Bibliographic Details
Published in:Environmental science & technology Vol. 14; no. 12; pp. 1524 - 1528
Main Authors: Means, Jay C, Wood, Susanne G, Hassett, John J, Banwart, Wayne L
Format: Journal Article
Language:English
Published: United States American Chemical Society 01-12-1980
Online Access:Get full text
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Summary:The sorption of pyrene, 3-methylcholanthrene, 7,12-dimethylbenz(A)anthracene, and dibenzanthracene on 14 soil and sediment samples exhibiting a wide range of physicochemical properties was studied. The equilibrium Freundlich constants and linear partition coefficients for each compound were highly correlated with the organic carbon content of the soils/sediments tested. No other significant correlations with soil/sediment properties were observed. The sorption constants when normalized to organic carbon content of the substrate predicted the octanol-water partition coefficients for the compounds tested. A highly significant negative correlation was observed between log substrate and log water solubility for these compounds. Experimental values of the water solubility and octanol-water partition coefficients for the four compounds are reported.
Bibliography:ark:/67375/TPS-DG5G2TD0-8
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ISSN:0013-936X
1520-5851
DOI:10.1021/es60172a005