Single-Step Preparation of Silver-Doped Magnetic Hybrid Nanoparticles for the Catalytic Reduction of Nitroarenes

• Published in: ACS omega Vol. 3; no. 3; pp. 3340 - 3347
• Main Authors: Chen, Hui-Fen, Hung, Mei-Jou, Hung, Tzu-Hsin, Tsai, Ya-Wen, Su, Chun-Wei, Yang, Jyisy, Huang, Genin Gary
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 31-03-2018
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.7b01987

This study adopts a simple but facile process for preparing silver-doped magnetic nanoparticles by the spontaneous oxidation–reduction/coprecipitation method. The preparation can be achieved in one pot with a single step, and the prepared silver-doped magnetic nanoparticles were utilized as nanocatalysts for the reduction of o-nitroaniline. Utilizing the magnetic characteristics of the prepared nanoparticles, the catalytic reactions can be carried out under quasi-homogeneous condition and the nanocatalysts can be easily collected after the conversion is achieved. It can be revealed from the results that the morphologies and the composition of the prepared silver-doped magnetic nanoparticles can be adjusted by changing the conditions during the production, which affects the efficacy of the catalysis. In addition, the catalysis efficiency is also controlled by the pH, temperature, and the amounts of nanocatalysts used during the catalytic reaction. Finally, the silver-doped magnetic nanocatalysts prepared in this study own the advantages of easy preparation, room-temperature catalysis, high conversion ability, and recyclability, which make them more applicable in real utilities.