Advanced Mercury Removal from Gold Leachate Solutions Prior to Gold and Silver Extraction:  A Field Study from an Active Gold Mine in Peru

• Published in: Environmental science & technology Vol. 36; no. 7; pp. 1636 - 1639
• Main Authors: Matlock, Matthew M, Howerton, Brock S, Van Aelstyn, Mike A, Nordstrom, Fredrik L, Atwood, David A
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 01-04-2002
• Subjects: 1,3-benzenediamidoethanethiol; Applied sciences; benzenediamidoethanethiol; Carbon - chemistry; Chelating Agents - chemistry; Chemical elements; Contamination; Earth sciences; Earth, ocean, space; Environmental Pollution - prevention & control; Exact sciences and technology; Global environmental pollution; Gold; Gold - chemistry; Gold mines & mining; Ligands; Mercury - chemistry; Metal geology; Metallic and non-metallic deposits; Metallurgy; Mining; Occupational Exposure - prevention & control; Occupational hazards; Peru; Pollution; Silver; South America; Peru; America; Complexation; Gold; Chemical precipitation; Pollution prevention; Thiolate; Ore extraction; Organic ligand; Mercury complex; Cyanides; NMR spectrometry; Cyano complex; X ray diffraction; Infrared spectrometry; Silver; Ore treatment; Chelating agent; Carboxamide; Raman spectrometry; Mining industry; Leachate; Environmental protection
• ISSN: 0013-936X; 1520-5851
• DOI: 10.1021/es0112285

Mercury contamination in the Gold−Cyanide Process (GCP) is a serious health and environmental problem. Following the heap leaching of gold and silver ores with NaCN solutions, portions of the mercury−cyano complexes often adhere to the activated carbon (AC) used to extract the gold. During the electrowinning and retorting steps, mercury can be (and often is) emitted to the air as a vapor. This poses a severe health hazard to plant workers and the local environment. Additional concerns relate to the safety of workers when handling the mercury-laden AC. Currently, mercury treatment from the heap leach solution is nonexistent. This is due to the fact that chelating ligands which can effectively work under the adverse pH conditions (as present in the heap leachate solutions) do not exist. In an effort to economically and effectively treat the leachate solution prior to passing over the AC, a dipotassium salt of 1,3-benzenediamidoethanethiol (BDET2-) has been developed to irreversibly bind and precipitate the mercury. The ligand has proven to be highly effective by selectively reducing mercury levels from average initial concentrations of 34.5 ppm (parts per million) to 0.014 ppm within 10 min and to 0.008 ppm within 15 min. X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), Raman, and infrared (IR) spectroscopy demonstrate the formation of a mercury−ligand compound, which remains insoluble over pH ranges of 0.0−14.0. Leachate samples from an active gold mine in Peru have been analyzed using cold vapor atomic fluorescence (CVAF) and inductively coupled plasma optical emission spectroscopy (ICP-OES) for metal concentrations before and after treatment with the BDET2- ligand.