A field experiment with variable-suction multi-compartment samplers to measure the spatio-temporal distribution of solute leaching in an agricultural soil

• Published in: Journal of contaminant hydrology Vol. 105; no. 3; pp. 131 - 145
• Main Authors: Bloem, E., Hogervorst, F.A.N., de Rooij, G.H.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 01-04-2009; [Amsterdam]: Elsevier Science B.V; Elsevier
• Subjects: agricultural soils; Agriculture; chlorides; Earth sciences; Earth, ocean, space; Exact sciences and technology; Field experiment; Filtration; Hot Temperature; Hydrogeology; Hydrology. Hydrogeology; infiltration (hydrology); leaching; Leaching surface; Metals - analysis; Pressure; samplers; sampling; Soil heterogeneity; Soil physics; Soil Pollutants - analysis; Solute transport; solutes; spatial variation; spring; temporal variation; Time Factors; Unsaturated flow; Volatilization; Water Movements; Water Pollutants, Chemical - analysis; winter; Soil physics; Leaching surface; Unsaturated flow; Solute transport; Soil heterogeneity; Field experiment; experimental studies; temporal distribution; time variations; dye tracers; springs; percolation; spatial resolution; soils; flow; chlorides; rainfall; solutes; sampling; suction; concentration; samplers; leaching; pressure; transport; halides; heterogeneity; in situ; depth; dilution; drainage; leachate
• ISSN: 0169-7722; 1873-6009
• DOI: 10.1016/j.jconhyd.2008.11.010

Solutes spread out in time and space as they move downwards from the soil surface with infiltrating water. Solute monitoring in the field is often limited to observations of resident concentrations, while flux concentrations govern the movement of solutes in soils. A recently developed multi-compartment sampler is capable of measuring fluxes at a high spatial resolution with minimal disturbance of the local pressure head field. The objective of this paper is to use this sampler to quantify the spatial and temporal variation of solute leaching below the root zone in an agricultural field under natural rainfall in winter and spring. We placed two samplers at 31 and 25 cm depth in an agricultural field, leaving the soil above undisturbed. Each sampler contained 100 separate cells of 31
×
31 mm. Water fluxes were measured every 5 min for each cell. We monitored leaching of a chloride pulse under natural rainfall by frequently extracting the collected leachate while leaving the samplers buried
in situ. This experiment was followed by a dye tracer experiment. This setting yielded information that widely surpassed the information that can be provided by separate anionic and dye tracer trials, and solute transport monitoring by coring or suction cups. The detailed information provided by the samplers showed that percolation at the sampling depth started much faster (approximately 3 h after the start of rainfall) in initially wet soil (pressure head above −
65 cm) than in drier soil (more than 14 h at pressure heads below −
80 cm). At any time, 25% of the drainage passed through 5–6% of the sampled area, reflecting the effect of heterogeneity on the flow paths. The amount of solute carried by individual cells varied over four orders of magnitude. The lateral concentration differences were limited though. This suggests a convective–dispersive regime despite the short vertical travel distance. On the other hand, the dilution index indicates a slight tendency towards stochastic–convective transport at this depth. There was no evidence in the observed drainage patterns and dye stained profiles of significant disturbance of the flow field by the samplers.