Constraints on the timing and conditions of high-grade metamorphism, charnockite formation and fluid-rock interaction in the Trivandrum Block, southern India

Incipient charnockites have been widely used as evidence for the infiltration of CO2‐rich fluids driving dehydration of the lower crust. Rocks exposed at Kakkod quarry in the Trivandrum Block of southern India allow for a thorough investigation of the metamorphic evolution by preserving not only ort...

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Published in:Journal of metamorphic geology Vol. 34; no. 6; pp. 527 - 549
Main Authors: Blereau, E., Clark, C., Taylor, R. J. M., Johnson, T. E., Fitzsimons, I. C. W., Santosh, M.
Format: Journal Article
Language:English
Published: Oxford Blackwell Publishing Ltd 01-08-2016
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Summary:Incipient charnockites have been widely used as evidence for the infiltration of CO2‐rich fluids driving dehydration of the lower crust. Rocks exposed at Kakkod quarry in the Trivandrum Block of southern India allow for a thorough investigation of the metamorphic evolution by preserving not only orthopyroxene‐bearing charnockite patches in a host garnet–biotite felsic gneiss, but also layers of garnet–sillimanite metapelite gneiss. Thermodynamic phase equilibria modelling of all three bulk compositions indicates consistent peak‐metamorphic conditions of 830–925 °C and 6–9 kbar with retrograde evolution involving suprasolidus decompression at high temperature. These models suggest that orthopyroxene was most likely stabilized close to the metamorphic peak as a result of small compositional heterogeneities in the host garnet–biotite gneiss. There is insufficient evidence to determine whether the heterogeneities were inherited from the protolith or introduced during syn‐metamorphic fluid flow. U–Pb geochronology of monazite and zircon from all three rock types constrains the peak of metamorphism and orthopyroxene growth to have occurred between the onset of high‐grade metamorphism at c. 590 Ma and the onset of melt crystallization at c. 540 Ma. The majority of metamorphic zircon growth occurred during protracted melt crystallization between c. 540 and 510 Ma. Melt crystallization was followed by the influx of aqueous, alkali‐rich fluids likely derived from melts crystallizing at depth. This late fluid flow led to retrogression of orthopyroxene, the observed outcrop pattern and to the textural and isotopic modification of monazite grains at c. 525–490 Ma.
Bibliography:ARC Discovery Project - No. DP150102773
istex:DFF545E6252513D933C97734EC337F07B6E5FAC7
ark:/67375/WNG-1L652QTS-G
ArticleID:JMG12192
ARC DECRA - No. DE120103067
Figure S1. Garnet-biotite gneiss T-X pseudosection with varying ferric iron content (O) from the XRF measured value of 0.39 (X = 0) to 0.01 (X = 1). Note that higher X values in this diagram actually correspond to lower XFe2O3 in the rock. A mid value of X = 0.7 (black line) was selected for the final P-T diagram. Figure S2. Charnockite P-X pseudosection with varying ferric iron content (O) from the XRF measured value of 0.35 (X = 0) to 0.01 (X = 1). Note that higher X values in this diagram actually correspond to lower XFe2O3 in the rock. A mid value of X = 0.7 (black line) was selected for the final P-T diagram. Figure S3. Metapelitic gneiss P-X pseudosection with varying ferric iron content (O) from the XRF measured value of 1.34 (X = 0) to 0.01 (X = 1). Note that higher X values in this diagram actually correspond to lower XFe2O3 in the rock. A mid value of X = 0.7 (black line) was selected for the final P-T diagram.Table S1. All data for monazite SHRIMP U-Pb analyses. Table S2. All data for zircon SHRIMP U-Pb analyses. Table S3. All data for monazite LA-ICP-MS REE and trace element analyses. Table S4. All data for zircon LA-ICP-MS REE and trace element analyses. Table S5. All data for garnet LA-ICP-MS REE and trace element analyses.
ISSN:0263-4929
1525-1314
DOI:10.1111/jmg.12192