Role of GO and Photoinitiator Concentration on Curing Behavior of PEG-Based Polymer for DLP 3D Printing
Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final dimension accuracy of the printed structures. In this study, the curing kinetics of liquid-light-curable resins, including water-dispersed gr...
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| Published in: | ACS omega Vol. 9; no. 3; pp. 3287 - 3294 |
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| Abstract | Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final dimension accuracy of the printed structures. In this study, the curing kinetics of liquid-light-curable resins, including water-dispersed graphene oxide (GO) and ultraviolet (UV)-cured acrylic resins, were investigated during digital light processing (DLP) 3D printing. Various stable composites of water-dispersed GO and UV-cured acrylic resin were prepared to fabricate 3D structures for cure-depth measurements. Several factors, including the UV-exposure conditions, photoinitiator concentration, and composition of the photopolymer resin, were found to significantly affect the cure-depth characteristics of the printed structures. The photocuring depth of the polymeric resin system was investigated as a function of the photoinitiator concentration. In addition, the study showed that the introduction of GO played a significant role in controlling the performance of the highly cross-linked network and the thickness of the cured layer. The curing characteristics of functional photocurable polymer-based DLP 3D printing contribute to process development and improvement of the quality of printed microstructures for industrial applications. |
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| AbstractList | Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final dimension accuracy of the printed structures. In this study, the curing kinetics of liquid-light-curable resins, including water-dispersed graphene oxide (GO) and ultraviolet (UV)-cured acrylic resins, were investigated during digital light processing (DLP) 3D printing. Various stable composites of water-dispersed GO and UV-cured acrylic resin were prepared to fabricate 3D structures for cure-depth measurements. Several factors, including the UV-exposure conditions, photoinitiator concentration, and composition of the photopolymer resin, were found to significantly affect the cure-depth characteristics of the printed structures. The photocuring depth of the polymeric resin system was investigated as a function of the photoinitiator concentration. In addition, the study showed that the introduction of GO played a significant role in controlling the performance of the highly cross-linked network and the thickness of the cured layer. The curing characteristics of functional photocurable polymer-based DLP 3D printing contribute to process development and improvement of the quality of printed microstructures for industrial applications. Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final dimension accuracy of the printed structures. In this study, the curing kinetics of liquid-light-curable resins, including water-dispersed graphene oxide (GO) and ultraviolet (UV)-cured acrylic resins, were investigated during digital light processing (DLP) 3D printing. Various stable composites of water-dispersed GO and UV-cured acrylic resin were prepared to fabricate 3D structures for cure-depth measurements. Several factors, including the UV-exposure conditions, photoinitiator concentration, and composition of the photopolymer resin, were found to significantly affect the cure-depth characteristics of the printed structures. The photocuring depth of the polymeric resin system was investigated as a function of the photoinitiator concentration. In addition, the study showed that the introduction of GO played a significant role in controlling the performance of the highly cross-linked network and the thickness of the cured layer. The curing characteristics of functional photocurable polymer-based DLP 3D printing contribute to process development and improvement of the quality of printed microstructures for industrial applications.Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final dimension accuracy of the printed structures. In this study, the curing kinetics of liquid-light-curable resins, including water-dispersed graphene oxide (GO) and ultraviolet (UV)-cured acrylic resins, were investigated during digital light processing (DLP) 3D printing. Various stable composites of water-dispersed GO and UV-cured acrylic resin were prepared to fabricate 3D structures for cure-depth measurements. Several factors, including the UV-exposure conditions, photoinitiator concentration, and composition of the photopolymer resin, were found to significantly affect the cure-depth characteristics of the printed structures. The photocuring depth of the polymeric resin system was investigated as a function of the photoinitiator concentration. In addition, the study showed that the introduction of GO played a significant role in controlling the performance of the highly cross-linked network and the thickness of the cured layer. The curing characteristics of functional photocurable polymer-based DLP 3D printing contribute to process development and improvement of the quality of printed microstructures for industrial applications. Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final dimension accuracy of the printed structures. In this study, the curing kinetics of liquid-light-curable resins, including water-dispersed graphene oxide (GO) and ultraviolet (UV)-cured acrylic resins, were investigated during digital light processing (DLP) 3D printing. Various stable composites of water-dispersed GO and UV-cured acrylic resin were prepared to fabricate 3D structures for cure-depth measurements. Several factors, including the UV-exposure conditions, photoinitiator concentration, and composition of the photopolymer resin, were found to significantly affect the cure-depth characteristics of the printed structures. The photocuring depth of the polymeric resin system was investigated as a function of the photoinitiator concentration. In addition, the study showed that the introduction of GO played a significant role in controlling the performance of the highly cross-linked network and the thickness of the cured layer. The curing characteristics of functional photocurable polymer-based DLP 3D printing contribute to process development and improvement of the quality of printed microstructures for industrial applications. |
| Author | Ha, Tai Hwan Jung, Yun Jae Nguyen, Men Thi Hong Jang, Woo Tae Ahn, Sang Jung Park, Eun Jin Kim, Young Heon Kim, Jong Hoon |
| AuthorAffiliation | Korea Research Institute of Standard and Science (KRISS) Department of Nanobiotechnology, KRIBB School of Biotechnology Core Research Facility Management Center Korea University of Science and Technology (UST) Graduate School of Analytical Science and Technology (GRAST) |
| AuthorAffiliation_xml | – name: Korea Research Institute of Standard and Science (KRISS) – name: Graduate School of Analytical Science and Technology (GRAST) – name: Korea University of Science and Technology (UST) – name: Department of Nanobiotechnology, KRIBB School of Biotechnology – name: Core Research Facility Management Center |
| Author_xml | – sequence: 1 givenname: Men Thi Hong surname: Nguyen fullname: Nguyen, Men Thi Hong organization: Graduate School of Analytical Science and Technology (GRAST) – sequence: 2 givenname: Jong Hoon surname: Kim fullname: Kim, Jong Hoon organization: Graduate School of Analytical Science and Technology (GRAST) – sequence: 3 givenname: Woo Tae surname: Jang fullname: Jang, Woo Tae organization: Graduate School of Analytical Science and Technology (GRAST) – sequence: 4 givenname: Yun Jae surname: Jung fullname: Jung, Yun Jae organization: Graduate School of Analytical Science and Technology (GRAST) – sequence: 5 givenname: Eun Jin surname: Park fullname: Park, Eun Jin organization: Korea University of Science and Technology (UST) – sequence: 6 givenname: Tai Hwan orcidid: 0000-0003-0892-3320 surname: Ha fullname: Ha, Tai Hwan organization: Korea University of Science and Technology (UST) – sequence: 7 givenname: Sang Jung surname: Ahn fullname: Ahn, Sang Jung email: sjahn@kriss.re.kr organization: Korea Research Institute of Standard and Science (KRISS) – sequence: 8 givenname: Young Heon orcidid: 0000-0001-9944-5859 surname: Kim fullname: Kim, Young Heon email: y.h.kim@cnu.ac.kr organization: Graduate School of Analytical Science and Technology (GRAST) |
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| Snippet | Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final... Photocuring kinetics in photopolymerization-based three-dimensional (3D) printing processes have gained significant attention because they determine the final... |
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| Title | Role of GO and Photoinitiator Concentration on Curing Behavior of PEG-Based Polymer for DLP 3D Printing |
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