Contactless Control of Local Surface Buckling in Photoaligned Gold/Liquid Crystal Polymer Bilayers

• Published in: Langmuir Vol. 34; no. 36; pp. 10543 - 10549
• Main Authors: de Haan, Laurens T, Willigers, Timo J. J, Wijkhuijs, Levina E. A, Hendrikx, Matthew, Nguyen, Cuong Thai, Leclère, Philippe, Souren, Anne E. J, Zhou, Guofu, Debije, Michael G
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 11-09-2018
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.8b01934

Wrinkling is a powerful technique for the preparation of surface structures over large areas, but it is difficult to simultaneously control the direction, period, and amplitude of the wrinkles without resorting to complicated procedures. In this work, we demonstrate a wrinkling system consisting of a liquid crystal polymer network and a thin layer of gold, in which the direction of the wrinkles is controlled by the alignment of the liquid crystal molecules and the average amplitude and period are controlled by a high-intensity UV irradiation. The UV exposure represses the amplitude and period dictated by the total exposure. Using photoalignment and photomasks, we demonstrate an unprecedented control over the wrinkling parameters and were able to generate some striking optical patterns. The mechanism of the wrinkle suppression was investigated and appears to involve localized photodegradation at the polymer–gold interface, possibly due to the formation of mechanoradicals.