Preparation of Allyl Sulfoxides by Palladium-Catalyzed Allylic Alkylation of Sulfenate Anions

Preparation of Allyl Sulfoxides by Palladium-Catalyzed Allylic Alkylation of Sulfenate Anions

Palladium-catalyzed allylic alkylation of sulfenate anions, generated from β-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.

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Bibliographic Details
Published in:Journal of organic chemistry Vol. 71; no. 19; pp. 7449 - 7454
Main Authors: Maitro, Guillaume, Prestat, Guillaume, Madec, David, Poli, Giovanni
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 15-09-2006
Subjects:
Chemistry
Exact sciences and technology
Organic chemistry
Michael addition
Anions
Catalytic reaction
Transition element complexes
Sulfenate
Sulfoxide
Palladium complex
Platinoid Complexes
Chemical synthesis
Alkylation
Allylic compound
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Description
Summary:Palladium-catalyzed allylic alkylation of sulfenate anions, generated from β-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.
Bibliography:ark:/67375/TPS-2QD18S1P-4
istex:EF499912E8F39D47BEE7632ED5D705F336687C59
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo061359u