Visualization of the Sol–Gel Transition in Porous Networks Using Fluorescent Viscosity-Sensitive Probes

• Published in: The journal of physical chemistry letters Vol. 15; no. 2; pp. 628 - 635
• Main Authors: Le Dizès Castell, Romane, Mirzahossein, Elham, Grzelka, Marion, Jabbari-Farouji, Sara, Bonn, Daniel, Shahidzadeh, Noushine
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 18-01-2024
• Subjects: Letter; Physical Insights into Materials and Molecular Properties
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.3c02634

The sol–gel transition involves the transformation of a colloidal suspension into a system-spanning, interconnected gel. This process is widely used to reinforce mechanically weakened porous artifacts, such as sculptures but the impact of the restricted geometry (porous network) on the gelation dynamics of the solution remains unclear. Here, using fluorescent viscosity-sensitive molecular rotors, confocal microscopy, and model pores, we visualize the local viscosity changes at the microscale that accompany the sol–gel transition of a methyltriethoxysilane solution into a gel network. We show that, with evaporation of the solvent, a viscosity gradient develops near the free surface, triggering the sol–gel transition inside small pores near the surface. In homogeneous porous media, this leads to skin formation, which reduces the evaporation rate. In heterogeneous porous media, a gradient in gel density develops toward the heart of the porous material, where the gel formation mainly occurs as capillary bridges within smaller pores.