The Optics of Chromophoric Dissolved Organic Matter (CDOM) in the Greenland Sea: An Algorithm for Differentiation between Marine and Terrestrially Derived Organic Matter

• Published in: Limnology and oceanography Vol. 46; no. 8; pp. 2087 - 2093
• Main Authors: Stedmon, C. A., Markager, S.
• Format: Journal Article
• Language: English
• Published: Waco, TX American Society of Limnology and Oceanography 01-12-2001
• Subjects: Cruises; Deep water; Dissolved organic matter; Earth sciences; Earth, ocean, space; Exact sciences and technology; External geophysics; Geochemistry; Greenland Sea; Mineralogy; North Sea; Oceans; Optical properties; Physical and chemical properties of sea water; Physics of the oceans; Sea water; Seas; Silicates; Standard deviation; Surface water; Water geochemistry; Wavelengths; Greenland Sea; Northeast Atlantic; North Atlantic; North Sea; sea water; algorithms; optical properties; marine environment; Atlantic Ocean; terrestrial environment; Arctic Ocean; organic materials; dissolved materials; optical methods
• ISSN: 0024-3590; 1939-5590
• DOI: 10.4319/lo.2001.46.8.2087

The optics of chromophoric dissolved organic matter (CDOM) in the Greenland Sea were investigated and compared to results from earlier studies in the Southeastern North Sea. Absorption at 375 nm (a375) in the Greenland Sea varied from 0.77 m-1to the detection limit of our instrument (0.05 m-1), with the highest values found during summer. The spectral slope coefficient (S) ranged from 8.2 to 26.4 μ m-1with the highest values occurring during winter. Seasonal variations in the in situ production and degradation of CDOM where shown to be responsible for the trends seen. A negative correlation between S and a375was evident in the Greenland Sea and differed noticeably from that found in coastal waters. The differing S-a375behavior of CDOM known to be of terrestrial origin allowed the development of an algorithm for the differentiation between marine and terrestrial organic matter. The behavior of marine CDOM was modeled by S = 7.4 + 1.1/a375.