Mechanistic Aspects of C−H Activation by Pt Complexes

Mechanistic Aspects of C−H Activation by Pt Complexes

Insight into the nature of C-H bond activation may have implications for important aspects of the technology that is needed for the proposed and intensely discussed hydrogen-based energy economy of the future. Lersch and Tilset discuss the C-H bond activation step in the Shilov cycle by limiting the...

Full description

Saved in:
Bibliographic Details
Published in:Chemical reviews Vol. 105; no. 6; pp. 2471 - 2526
Main Authors: Lersch, Martin, Tilset, Mats
Format: Journal Article
Language:English
Published: United States American Chemical Society 01-06-2005
Subjects:
Catalysis
Chemical reactions
Energy
Gases
Hydrocarbons - chemistry
Hydrogen bonds
Ions
Kinetics
Molecular Conformation
Organoplatinum Compounds - chemical synthesis
Organoplatinum Compounds - chemistry
Protons
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Insight into the nature of C-H bond activation may have implications for important aspects of the technology that is needed for the proposed and intensely discussed hydrogen-based energy economy of the future. Lersch and Tilset discuss the C-H bond activation step in the Shilov cycle by limiting the research to the mechanistic behavior of molecular entities that exist in solution-significant contributions from studies of small Pt-based ions in the gas phase.
Bibliography:istex:CB1809A9FE7B483BB7854BDFA26103EC4067EE16
ark:/67375/TPS-6DF825QF-X
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-3
content type line 23
ObjectType-Review-2
ISSN:0009-2665
1520-6890
DOI:10.1021/cr030710y