Heavy mineral analysis by ICP-AES a tool to aid sediment provenancing

• Published in: Journal of geochemical exploration Vol. 184; pp. 1 - 10
• Main Authors: Mounteney, I., Burton, A.K., Farrant, A.R., Watts, M.J., Kemp, S.J., Cook, J.M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-01-2018
• Subjects: Geochemistry; Heavy minerals; ICP-AES; Provenance studies; United Arab Emirates; ICP-AES; Geochemistry; Provenance studies; Heavy minerals; United Arab Emirates
• ISSN: 0375-6742; 1879-1689
• DOI: 10.1016/j.gexplo.2017.10.007

Correlation and provenancing of sediments/sedimentary rocks can be achieved by several techniques; a common approach is through the identification and quantification of heavy minerals using a petrological microscope. This can be time consuming, the analysis of heavy minerals by inductively coupled plasma atomic emission spectroscopy offers a faster alternative, by determining key elements associated with specific heavy minerals. Here we outline a method for determining heavy mineral species though ICP-AES using high temperature fusion with a lithium metaborate flux to ensure complete dissolution of resistate minerals. The method was tested in a provenance study of desert sands from the United Arab Emirates. The results are compared with those derived from traditional optical microscopy. These show good agreement for minerals with specific geochemical signatures, whilst the overall geochemistry of the heavy mineral concentrate was diagnostic of potential sediment sources. This geochemical approach is capable of processing large numbers of samples rapidly and is advocated as a screening technique. A combination of geochemical and mineralogical data produced by these techniques provides a powerful diagnostic tool for studies of heavy mineral signatures in sediments frequently used in mineral reconnaissance, paleogeographic reconstruction and reservoir characterisation in the petroleum industry.
•Analysis of heavy minerals by ICP-AES can determine key elements associated with specific heavy minerals.•Capable of processing large numbers of samples rapidly as a screening technique.•Used in defining heavy mineral signatures in key sediments associated with conventional and unconventional energy, mineral reconnaissance and paleogeographic reconstruction.