Discovery of Polyoxo-Noble-Metalate-Based Metal–Organic Frameworks

Discovery of Polyoxo-Noble-Metalate-Based Metal–Organic Frameworks

Here we report on the synthesis, structure, and characterization of the first example of a poly­oxo­palladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate­(II) nanocubes [Pd13O8(AsO4)8H6]8– decorated by four Ba2+ ions on each of two...

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 141; no. 8; pp. 3385 - 3389
Main Authors: Bhattacharya, Saurav, Ayass, Wassim W, Taffa, Dereje H, Schneemann, Andreas, Semrau, A. Lisa, Wannapaiboon, Suttipong, Altmann, Philipp J, Pöthig, Alexander, Nisar, Talha, Balster, Torsten, Burtch, Nicholas C, Wagner, Veit, Fischer, Roland A, Wark, Michael, Kortz, Ulrich
Format: Journal Article
Language:English
Published: United States American Chemical Society 27-02-2019
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Summary:Here we report on the synthesis, structure, and characterization of the first example of a poly­oxo­palladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate­(II) nanocubes [Pd13O8(AsO4)8H6]8– decorated by four Ba2+ ions on each of two opposite faces. These secondary building units (SBUs) are linked to each other via rigid linear organic groups, resulting in a stable 3D POP-MOF framework, which exhibits interesting sorption as well as catalytic properties.
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ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.8b13397