Carbon Monoxide Free Aminocarbonylation of Aryl and Alkenyl Iodides Using DMF as an Amide Source

Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.

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Bibliographic Details
Published in:Organic letters Vol. 4; no. 17; pp. 2849 - 2851
Main Authors: Hosoi, Kazushi, Nozaki, Kyoko, Hiyama, Tamejiro
Format: Journal Article
Language:English
Published: United States American Chemical Society 22-08-2002
Online Access:Get full text
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Description
Summary:Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol026236k