Glycosaminoglycan-Mimetic Biomaterials. 1. Nonsulfated and Sulfated Glycopolymers by Cyanoxyl-Mediated Free-Radical Polymerization

A series of N-acetyl-D-glucosamine-containing glycomonomers was synthesized as an initial step in the synthesis of glycosaminoglycanmimetic glycopolymers. It was shown that cyanoxyl-mediated free-radical polymerization is an original and straightforward approach for obtaining water-soluble glycopoly...

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Bibliographic Details
Published in:	Macromolecules Vol. 33; no. 4; pp. 1123 - 1125
Main Authors:	Grande, D, Baskaran, S, Baskaran, C, Gnanou, Y, Chaikof, E. L
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 22-02-2000
Subjects:	Amines Applied sciences Biomaterials Catalysts Copolymerization Exact sciences and technology Free radical polymerization Free radicals Glucose Nuclear magnetic resonance spectroscopy Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Size exclusion chromatography Monodispersed polymer Side chain Aminoglycoside Preparation Acrylamide copolymer Organic sulfate Glycosaminoglycan Olefin derivative copolymer Radical copolymerization Experimental study
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Summary:	A series of N-acetyl-D-glucosamine-containing glycomonomers was synthesized as an initial step in the synthesis of glycosaminoglycanmimetic glycopolymers. It was shown that cyanoxyl-mediated free-radical polymerization is an original and straightforward approach for obtaining water-soluble glycopolymers with high monosaccharide contents and low polydispersity indexes.
Bibliography:	istex:45E7DE0A43D5999C2702C7CD04F13EC248F08DC7 ark:/67375/TPS-750T5T8N-9 ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
ISSN:	0024-9297 1520-5835
DOI:	10.1021/ma991579s