Microbubbles for Effective Cleaning of Metal Surfaces Without Chemical Agents

• Published in: Langmuir Vol. 38; no. 2; pp. 769 - 776
• Main Authors: Li, Pan, Wang, JiaHao, Liao, ZhengHao, Ueda, Yoshikatsu, Yoshikawa, Kiyoshi, Zhang, GuoXing
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 18-01-2022
• Subjects: Hydrodynamics; Metals; Microbubbles; Waste Water
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.1c02769

Traditional cleaning methods involving surfactants and ultrasound generate large amounts of wastewater. Microbubbles offer a more eco-friendly technology for interface cleaning. Here, we explored the efficiency of microbubbles for cleaning oil from metal surfaces. Air microbubbles at concentrations as high as 106 particles/mL were generated by hydrodynamic cavitation. Under optimal conditions, cleaning efficiencies for the removal of oil from carbon-steel and stainless-steel surfaces were 78.5 and 49.8% after 15 min, respectively, compared to only 6.5 and 9.9% without microbubbles. Additionally, combining microbubble treatment with the ultrasonic method achieved a higher efficiency than ultrasonic cleaning alone, achieving an efficiency of 85.5% after 3 min compared to 69.0%. The mechanism of microbubble cleaning was determined using a fluorescence observation system, and a model was established to describe the cleaning process. The use of microbubbles produced less emulsified oil wastewater because the oil that attaches to the microbubble surface floats with the bubbles to the surface of the cleaning water, where it can be removed, allowing for water recycling. This novel microbubble cleaning technology, which both enhances cleaning efficiency and reduces wastewater production, represents a viable and eco-friendly option for degreasing processes.