The Enantioselective Tsuji Allylation

The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry.

Saved in:

Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 126; no. 46; pp. 15044 - 15045
Main Authors:	Behenna, Douglas C, Stoltz, Brian M
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 24-11-2004
Subjects:	Chemical reactivity Chemistry Exact sciences and technology Organic chemistry Reactivity and mechanisms Catalytic reaction Organic carbonate Enantioselectivity Palladium Complexes Catalyst selectivity Transition metal Complexes Complex catalyst Experimental study Allylation Asymmetric reaction Platinoid Complexes Enol ether Catalyst activity
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Description
Summary:	The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry.
Bibliography:	ark:/67375/TPS-8CS7JVJS-K istex:020997F7EB44B15EBBFE98F076C99020E45E0ED4 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja044812x