Rhodium(III)-Catalyzed Selective C–H Acetoxylation and Hydroxylation Reactions
An efficient Cp*Rh(III)-catalyzed, chelation-assisted C(sp2)–H acetoxylation and hydroxylation reaction has been developed for the first time. The reaction proceeds under mild conditions and allows for selective preparation of C–H acetoxylation and hydroxylation products, thus providing a good com...
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| Published in: | Organic letters Vol. 19; no. 13; pp. 3532 - 3535 |
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| Main Authors: | , |
| Format: | Journal Article |
| Language: | English |
| Published: |
United States
American Chemical Society
07-07-2017
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| Online Access: | Get full text |
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| Summary: | An efficient Cp*Rh(III)-catalyzed, chelation-assisted C(sp2)–H acetoxylation and hydroxylation reaction has been developed for the first time. The reaction proceeds under mild conditions and allows for selective preparation of C–H acetoxylation and hydroxylation products, thus providing a good complement to previous C–H oxygenation reactions and expanding the field of Cp*Rh(III)-catalyzed C–H functionalizations. |
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| Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/acs.orglett.7b01494 |