Phosphole-Containing Hybrid Calixpyrroles:  New Multifunctional Macrocyclic Ligands for Platinum(II) Ions

Phosphole-Containing Hybrid Calixpyrroles:  New Multifunctional Macrocyclic Ligands for Platinum(II) Ions

Phosphole-containing hybrid calixpyrroles have been prepared by acid-promoted condensation reactions. σ3-Calix[1]phosphole[1]thiophene[2]pyrrole reacts with PtCl2(COD) to afford an unusual type of macrocyclic Pt(II)−monophosphine complex bearing a η3-cyclooctadienyl ligand, in which the phosphole an...

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Bibliographic Details
Published in:Organometallics Vol. 25; no. 13; pp. 3105 - 3107
Main Authors: Matano, Yoshihiro, Nakabuchi, Takashi, Miyajima, Tooru, Imahori, Hiroshi
Format: Journal Article
Language:English
Published: American Chemical Society 19-06-2006
Online Access:Get full text
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Summary:Phosphole-containing hybrid calixpyrroles have been prepared by acid-promoted condensation reactions. σ3-Calix[1]phosphole[1]thiophene[2]pyrrole reacts with PtCl2(COD) to afford an unusual type of macrocyclic Pt(II)−monophosphine complex bearing a η3-cyclooctadienyl ligand, in which the phosphole and pyrrole units bind the Pt−Cl moiety through cooperative, noncovalent bonding interactions.
Bibliography:istex:E9D26E8F4AD3C6BA0D4C4BA1A796AF9A91FEA4FA
ark:/67375/TPS-637RT24Z-T
ISSN:0276-7333
1520-6041
DOI:10.1021/om060300a