Kinetic and thermodynamic effects in the thermal electrocyclic ring-openings of 3-fluorocyclobutene, 3,3-difluorocyclobutene, and 3-(trifluoromethyl)cyclobutene

Kinetic and thermodynamic effects in the thermal electrocyclic ring-openings of 3-fluorocyclobutene, 3,3-difluorocyclobutene, and 3-(trifluoromethyl)cyclobutene

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 112; no. 1; pp. 363 - 367
Main Authors: Dolbier, William R, Gray, Thomas A, Keaffaber, Jeffrey J, Celewicz, Lech, Koroniak, Henryk
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 1990
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Temperature
Electrocyclic reaction
Medium effect
Activation parameter
Fluorocarbon
Thermal reaction
Rate constant
Thermodynamic properties
Monocyclic compound
Ethylenic compound
Ring cleavage
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Description
Bibliography:istex:8DBA25C601E3C0A70B77DC842AF7B5FE49FFCF8B
ark:/67375/TPS-JLNH1743-G
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00157a055