Synthesis, Structure, and Bonding in Zirconocene Primary Phosphido (PHR-), Phosphinidene (PR2-), and Phosphide (P3-) Derivatives

• Published in: Organometallics Vol. 13; no. 5; pp. 1918 - 1926
• Main Authors: Ho, Jianwei, Rousseau, Roger, Stephan, Douglas W
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 01-05-1994
• Subjects: Chemistry; Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; Organic chemistry; Organic compounds; Organometalloidal and organometallic compounds; Physics; Preparations and properties; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Transition metals derivatives; Phosphido complex; Zirconium III Zirconium IV Complexes; Molecular structure; Secondary phosphine; Orbital interaction; Zirconium Organic compounds; Trivalent metal Complexes; Metallocene; Phosphorus Organic compounds; Diamagnetic materials; Paramagnetic materials; Reaction mechanism; Chloro complex; EPR spectrum; Mixed oxidation number; Frontier orbital; Trinuclear complex; Organic ligand; Theoretical study; Transition metal Complexes; Tetravalent metal Complexes; Experimental study; X ray diffraction; Hydrido complex; Mu complex; Fenske Hall method; Dinuclear complex; Extended Hueckel method; NMR spectrum; Crystalline structure
• ISSN: 0276-7333; 1520-6041
• DOI: 10.1021/om00017a056