Highly Selective Oxidative Cleavage of β-Cyclodextrin−Epoxide/Aziridine Complexes with IBX in Water

Water, an environmentally friendly reaction medium, has been utilized for the reaction of IBX with various epoxides 1 and aziridines 2 as their β-cyclodextrin complexes to afford for the first time α-hydroxyketones 3 and α-aminoketones 4, respectively.

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Bibliographic Details
Published in:	Journal of organic chemistry Vol. 68; no. 23; pp. 9119 - 9121
Main Authors:	Surendra, K, Krishnaveni, N. Srilakshmi, Reddy, M. Arjun, Nageswar, Y. V. D, Rao, K. Rama
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 14-11-2003
Subjects:	Aliphatic compounds Chemistry Exact sciences and technology Organic chemistry Preparations and properties Water Aminoketone Nitrogen heterocycle Ketol Epoxide Aziridine derivatives Oxidation Selectivity Oxygen heterocycle Chemical synthesis Complexes
Online Access:	Get full text
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Description
Summary:	Water, an environmentally friendly reaction medium, has been utilized for the reaction of IBX with various epoxides 1 and aziridines 2 as their β-cyclodextrin complexes to afford for the first time α-hydroxyketones 3 and α-aminoketones 4, respectively.
Bibliography:	istex:F1321AC0652B1E8931DB4656895FA4020DD56071 ark:/67375/TPS-DMZC9PNX-M IICT Communication No. 020911 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo034079c