Novel Reversible Ionic-to-Covalent Transition in a Highly Conducting TTF Derivative

TTF produces two completely different phenomena with the different isomers of chloranil; with the para isomer it produces an insulating, alternating stack, ambient temperature neutral solid. While with the ortho isomer, it produces a more interesting system consisting of interconvertible conducting...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 125; no. 52; pp. 16206 - 16207
Main Authors:	Kwang-Fu Shen, Clifton, Duong, Hieu M, Sonmez, Gursel, Wudl, Fred
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 31-12-2003
Subjects:	Condensed matter: electronic structure, electrical, magnetic, and optical properties Conductivity of specific materials Electronic transport in condensed matter Exact sciences and technology Physics Polymers; organic compounds (including organic semiconductors) Electrical conductivity Electrical properties Organic conductors Benzoquinone derivatives TTF Experimental study Cyclic voltammetry Sulfur heterocycle Molecular complex Electronic transition Monocyclic compound EPR spectroscopy Organic compounds
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Summary:	TTF produces two completely different phenomena with the different isomers of chloranil; with the para isomer it produces an insulating, alternating stack, ambient temperature neutral solid. While with the ortho isomer, it produces a more interesting system consisting of interconvertible conducting ionic and covalent components.
Bibliography:	ark:/67375/TPS-MCVZB1GH-B istex:27E5D3B08332147ACBCDC76C8B0AFDE7A9C1DB6D ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja037621n