The 2,6-Diisocyanoazulene Motif: Synthesis and Efficient Mono- and Heterobimetallic Complexation with Controlled Orientation of the Azulenic Dipole

Synthesis of the remarkably air- and thermally stable 2,6-diisocyano-1,3-diethoxycarbonylazulene linker from 2-amino-1,3-diethoxycarbonylazulene in 57% cumulative yield was developed. Incorporation of the ester “arms” in the design of this first diisocyanoazulene bridge permitted fully controlled st...

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Bibliographic Details
Published in:	Journal of the American Chemical Society Vol. 128; no. 7; pp. 2300 - 2309
Main Authors:	Holovics, Thomas C, Robinson, Randall E, Weintrob, Edward C, Toriyama, Masaharu, Lushington, Gerald H, Barybin, Mikhail V
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 22-02-2006
Subjects:	Carbonyl and nitrosyl compounds, and their complexes Carbonyl and nitrosyl metals Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Physics Preparations and properties Structure of solids and liquids; crystallography Structure of specific crystalline solids Molecular structure Chromium Carbonyl Complexes Organic ligand Transition metal Carbonyl Complexes Inorganic synthesis X ray diffraction Regiospecificity Electronic structure Heteronuclear complex Dinuclear complex Bicyclic compound Aromatic compound Charge transfer compound Tungsten Carbonyl Complexes Ultraviolet visible spectrometry Crystalline structure
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