A Stable Three-Coordinate Rhodium(I) Olefin Complex

A Stable Three-Coordinate Rhodium(I) Olefin Complex

Reaction of LLi (L = ArNC(Me)CHC(Me)NAr, Ar = 2,6-Me2C6H3) with [Rh(COE)2Cl]2 (COE = cyclooctene) produces stable, three-coordinate LRh(COE) (1). At room temperature in solution, the LRh fragment moves rapidly over one face of the COE ligand via reversible allyl hydride formation.

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Bibliographic Details
Published in:Organometallics Vol. 17; no. 19; pp. 4121 - 4123
Main Authors: Budzelaar, Peter H. M, de Gelder, Rene, Gal, Anton W
Format: Journal Article
Language:English
Published: American Chemical Society 14-09-1998
Online Access:Get full text
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Description
Summary:Reaction of LLi (L = ArNC(Me)CHC(Me)NAr, Ar = 2,6-Me2C6H3) with [Rh(COE)2Cl]2 (COE = cyclooctene) produces stable, three-coordinate LRh(COE) (1). At room temperature in solution, the LRh fragment moves rapidly over one face of the COE ligand via reversible allyl hydride formation.
Bibliography:ark:/67375/TPS-1KPZQHG3-F
istex:6956B659C1002EF6950D2B4A741F3CB042D62D81
ISSN:0276-7333
1520-6041
DOI:10.1021/om980580x