STM Study of Copper Growth on ZnO(0001)−Zn and ZnO(0001̄)−O Surfaces

• Published in: The journal of physical chemistry. B Vol. 107; no. 38; pp. 10583 - 10590
• Main Authors: Koplitz, Lynn Vogel, Dulub, Olga, Diebold, Ulrike
• Format: Journal Article
• Language: English
• Published: American Chemical Society 25-09-2003
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp0352175

The room-temperature growth of Cu on the polar (0001)-Zn and (0001̄)-O surfaces of zinc oxide has been studied with scanning tunneling microscopy (STM). Copper grows on the (0001)-Zn surface as three-dimensional clusters even at low coverages (0.05−0.25 monolayers (ML)); two-dimensional (2D) islands are only observed at very low coverages (0.001−0.05 ML). The average size of the 3D clusters increases with coverage, and their density increases slowly. Surface roughness and sputter damage change the growth mode to more 2D-like. The Cu clusters are well-separated and exhibit a well-defined hexagonal shape. Equilibrium crystal shape analysis yields an apparent work of adhesion of 3.4 ± 0.1 J/m2 for the largest clusters. On the (0001̄)-O surface, formation of two-dimensional Cu clusters was observed at coverages of less than 0.1 ML.