Drag Forces on a Stationary Particle in Flowing Two-Dimensional Ordered Particle Monolayers:  Simulation and Measurement Using Optical Tweezers

• Published in: Langmuir Vol. 18; no. 24; pp. 9587 - 9593
• Main Authors: Aveyard, R, Binks, B. P, Clint, J. H, Fletcher, P. D. I, Neumann, B, Paunov, V. N, Annesley, J, Botchway, S. W, Parker, A. W, Ward, A. D, Burgess, A. N
• Format: Journal Article
• Language: English
• Published: American Chemical Society 26-11-2002
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la020578h

Using a laser tweezer method, we have studied the drag force on a charged polystyrene latex particle adsorbed at the oil−water interface when an ordered 2D monolayer of identical particles is flowed around it. The drag force, measured as a function of the flow velocity and the lattice spacing in the particle monolayer, contains contributions from long-range electrostatic forces between the particles at the liquid interface. The interpretation of the experimental results is based on a model in which the repulsion arises primarily from the presence of a very small net electric charge at the particle−oil interface. This charge corresponds to a fractional ionization of the sulfate groups present at the particle surface exposed to the oil phase which is estimated from an independent experiment (see Aveyard, R.; Binks, B. P.; Clint, J. H.; Fletcher, P. D. I.; Horozov, T. S.; Neumann, B.; Paunov, V. N.; Annesley, J.; Botchway, S. W.; Nees, D.; Parker, A. W.; Ward, A. D.; Burgess, A. N. Phys. Rev. Lett. 2002, 88, 246102-1) to be approximately 3.3 × 10-4 for the latex sample used. The experimentally determined drag forces are in reasonable agreement with results from computer simulations for a range of values of the velocity and the lattice spacing of the particle monolayer.