Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold

Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild...

Full description

Saved in:
Bibliographic Details
Published in:Organometallics Vol. 35; no. 19; pp. 3344 - 3349
Main Authors: Mellone, Irene, Gorgas, Nikolaus, Bertini, Federica, Peruzzini, Maurizio, Kirchner, Karl, Gonsalvi, Luca
Format: Journal Article
Language:English
Published: American Chemical Society 10-10-2016
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Fe­(II) hydrido carbonyl complexes supported by PNP pincer ligands based on the 2,6-diaminopyridine scaffold were studied as homogeneous, non-precious-metal-based catalysts for selective formic acid dehydrogenation to hydrogen and carbon dioxide, reaching quantitative yields and high TONs under mild reaction conditions.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.6b00551