Dissociation Constants of Parabens and Limiting Conductances of Their Ions in Water

• Published in: The journal of physical chemistry. B Vol. 116; no. 4; pp. 1385 - 1392
• Main Authors: Kroflič, Ana, Apelblat, Alexander, Bešter-Rogač, Marija
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 02-02-2012
• Subjects: Anions; Aqueous solutions; Conductivity; Constants; Constraining; Electric Conductivity; Entropy; Ions - chemistry; Mathematical analysis; Parabens - chemistry; Resistivity; Solutions; Temperature; Water - chemistry
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp211150p

Precise measurements of electrical conductivities of methylparaben, ethylparaben, propylparaben, and butylparaben sodium salts in dilute aqueous solutions were performed from 278.15 to 313.15 K in 5 K intervals. Experimental conductivity data were analyzed applying the Quint–Viallard conductivity equations by taking into account the salt hydrolysis in aqueous solutions. These evaluations yield the limiting conductances of paraben anions and the dissociation constants of the investigated parabens in water. From temperature dependence of dissociation constants, the thermodynamic functions associated with the dissociation process were estimated. It was discovered that the contributions of enthalpy and entropy to the Gibbs free energy are quite similar. The Walden products of paraben anions in water are independent of temperature, indicating that the hydrodynamic radii are not significantly affected by temperature.