Electrochemical Isothiocyanation of Primary Amines

Electrochemical Isothiocyanation of Primary Amines

Isothiocyanates are ubiquitous building blocks used across the fields. Nevertheless, their classical syntheses very often rely on the use of toxic and expensive reagents. Herein, we report a new practical, mild, high-yielding, and supporting-electrolyte-free electrochemical method for the preparatio...

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Bibliographic Details
Published in:Organic letters Vol. 25; no. 7; pp. 1147 - 1150
Main Authors: Kiaku, Cyrille, Walsh, Jamie M., Leech, Matthew C., Poole, Darren L., Mason, Joseph, Goodall, Iain C. A., Devo, Perry, Lam, Kevin
Format: Journal Article
Language:English
Published: United States American Chemical Society 24-02-2023
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Summary:Isothiocyanates are ubiquitous building blocks used across the fields. Nevertheless, their classical syntheses very often rely on the use of toxic and expensive reagents. Herein, we report a new practical, mild, high-yielding, and supporting-electrolyte-free electrochemical method for the preparation of aliphatic and aromatic isothiocyanates from amine and carbon disulfide.
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ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.3c00128