Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.

Saved in:
Bibliographic Details
Published in:Journal of organic chemistry Vol. 75; no. 4; pp. 1197 - 1202
Main Authors: Ramón, Rubén S, Bosson, Johann, Díez-González, Silvia, Marion, Nicolas, Nolan, Steven P
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 19-02-2010
Subjects:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Silver
Gold
Chemical rearrangement
Catalytic reaction
Aldoxime
Carboxamide
Silver compound
Transition metal
Primary amide
Catalysis
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo902461a