Ligand-Free Iron-Catalyzed Carbon(sp2)–Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides

Ligand-Free Iron-Catalyzed Carbon(sp2)–Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides

An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to good yields. This new iron-catalyzed cross-coupling reaction provides a mild, inexpensive, and environmentally friendly avenue toward synthesi...

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Bibliographic Details
Published in:Journal of organic chemistry Vol. 83; no. 12; pp. 6325 - 6333
Main Authors: Liu, Qiang, Wang, Zhi-Yong, Peng, Xiao-Shui, Wong, Henry N. C
Format: Journal Article
Language:English
Published: United States American Chemical Society 15-06-2018
Online Access:Get full text
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Summary:An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to good yields. This new iron-catalyzed cross-coupling reaction provides a mild, inexpensive, and environmentally friendly avenue toward synthesis of diversified diene derivatives.
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ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.8b00510