Spectroscopic analysis, coordination geometry, and x-ray structures of nickel(II) compounds with sterically demanding tris(pyrazolyl)borate ligands and azide or (thio)cyanate anions. Crystal and molecular structures of bis[(.mu.-thiocyanato-N,S)(hydrotris(3-isopropyl-4-bromopyrazol-1-yl)borato)nickel(II)]-3-heptane and (thiocyanato-N)(hydrotris(3-tert-butyl-5-methylpyrazol-1-yl)borato)nickel(II)

• Published in: Inorganic chemistry Vol. 31; no. 19; pp. 3943 - 3950
• Main Authors: Trofimenko, S, Calabrese, J. C, Kochi, J. K, Wolowiec, S, Hulsbergen, F. B, Reedijk, J
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 01-09-1992
• Subjects: Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; Inorganic compounds; Metal complexes; Physics; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Five membered ring; Molecular structure; Nitrogen heterocycle; Organic ligand; Transition metal Complexes; Experimental study; X ray diffraction; Azido complex; Inorganic compound; Isothiocyanato complex; Mu complex; Preparation; Ligand field; Dinuclear complex; Boron Organic compounds; Bromine Organic compounds; Infrared spectrum; Isocyanato complex; Tridentate ligand; Nickel II Complexes; Crystalline structure
• ISSN: 0020-1669; 1520-510X
• DOI: 10.1021/ic00045a017