Regulation of the Deposition Morphology of Inkjet-Printed Crystalline Materials via Polydopamine Functional Coatings for Highly Uniform and Electrically Conductive Patterns

• Published in: ACS applied materials & interfaces Vol. 8; no. 33; pp. 21750 - 21761
• Main Authors: Liu, Liang, Ma, Siyuan, Pei, Yunheng, Xiong, Xiao, Sivakumar, Preeth, Singler, Timothy J
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 24-08-2016
• Subjects: polydopamine; coffee ring effect; plasma reduction; interfacial crystallization; inkjet printing; reactive silver ink; deposition morphology control
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.6b03063

We report a method to achieve highly uniform inkjet-printed silver nitrate (AgNO3) and a reactive silver precursor patterns on rigid and flexible substrates functionalized with polydopamine (PDA) coatings. The printed AgNO3 patterns on PDA-coated substrates (glass and polyethylene terephthalate (PET)) exhibit a narrow thickness distribution ranging between 0.9 and 1 μm in the line transverse direction and uniform deposition profiles in the line axial direction. The deposited reactive silver precursor patterns on PDA-functionalized substrates also show “dome-shaped” morphology without “edge-thickened” structure due to “coffee-stain” effect. We posit that the highly uniform functional ink deposits formed on PDA-coated substrates are attributable to the strong binding interaction between the abundant catecholamine moieties at the PDA surface and the metallic silver cations (Ag+ or Ag­(NH3)2+) in the solutal inks. During printing of the ink rivulet and solvent evaporation, the substrate–liquid ink (S–L) interface is enriched with the silver-based cations and a solidification at the S/L interface is induced. The preferential solidification initiated at the S–L interface is further verified by the in situ visualization of the dynamic solidification process during solvent evaporation, and results suggest an enhanced crystal nucleation and growth localized at the S–L interface on PDA functionalized substrates. This interfacial interaction mediates solute transport in the liquid phase, resulting in the controlled enrichment of solute at the S–L interface and mitigated solute precipitation in both the contact line region and the liquid ink–vapor (L–V) interface due to evaporation. This mediated transport contributes to the final uniform solid deposition for both types of ink systems. This technique provides a complementary strategy for achieving highly uniform inkjet-printed crystalline structures, and can serve as an innovative foundation for high-precision additive delivery of functional materials.