Effect of Sophorolipid Adsorption on the Coal Microstructure: Experimental and Wettability Mathematical Model Discussion

• Published in: Langmuir Vol. 39; no. 39; pp. 14173 - 14188
• Main Authors: Wang, Shiju, Zheng, Yuannan, Jiang, Bingyou, Yu, Chang-Fei, Zhang, Yi, Tao, Wenhan, Ji, Ben
• Format: Journal Article
• Language: English
• Published: American Chemical Society 03-10-2023
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/acs.langmuir.3c02308

Green biosurfactants are emerging as a promising area of research. However, there is a limited focus on the adsorption and wetting characteristics of biosurfactants on coal dust. This study explores the effects of sophorolipid (SL) biosurfactants on the microstructure and wettability of different coalification degree coal. The microstructure parameters of SL adsorbed on coal dust were measured using a surface tensiometer, contact angle analyzer, and particle size analyzer. The results indicate that SL has the lowest critical surface tension, leading to a 9.25° decrease in the contact angle for low-rank bituminous coal (YZ-LRBC). Furthermore, SL significantly altered the particle size distribution of lignite (NM-LC) and YZ-LRBC. The pore size structure of SL-infiltrated coal dust was quantified using a specific surface area analyzer, revealing a decrease in the specific surface area and an increase in the average pore size. The infrared analysis demonstrated that SL permeation significantly increased the percentage of hydrophilic functional groups (hydroxyl structures) while reducing the hydrophobic functional groups (aliphatic hydrocarbon and aromatic structure). Based on the measured microstructure parameters, a regression equation for contact angle was established: [contact angle (°)] = 73.800 – 0.860 × [D10 (nm)] + 4.280 × [specific surface area (m2/g)]. Notably, the characteristic particle size D10 had a significant negative effect on the contact angle, while the specific surface area had a significant positive effect. These findings provide a theoretical foundation for the application of biosurfactants in water injection to reduce dust and improve the wetting efficiency.