Slow-Light-Enhanced Polarization Division Multiplexing Infrared Absorption Spectroscopy for On-Chip Wideband Multigas Detection in a 1D Photonic Crystal Waveguide

• Published in: Analytical chemistry (Washington) Vol. 96; no. 8; pp. 3445 - 3453
• Main Authors: Peng, Zihang, Huang, Yijun, Zheng, Kaiyuan, Min, Yuting, Zhao, Huan, Pi, Mingquan, Song, Fang, Zheng, Chuantao, Zhang, Yu, Chang, Zhiyong, Wang, Yiding
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 27-02-2024
• Subjects: Absorption spectroscopy; Acetylene; Bandwidths; Broadband; Gas sensors; Infrared absorption; Infrared detectors; Infrared spectroscopy; Lasers; Light; Methane; Multiplexing; Photonic crystals; Polarization; Sensors; Spectrum analysis; Waveguides
• ISSN: 0003-2700; 1520-6882
• DOI: 10.1021/acs.analchem.3c04793

Slow-light photonic crystal waveguide (PCW) gas sensors based on infrared absorption spectroscopy play a pivotal role in enhancing the on-chip interaction between light and gas molecules, thereby significantly boosting sensor sensitivity. However, two-dimensional (2D) PCWs are limited by their narrow mode bandwidth and susceptibility to polarization, which restricts their ability for multigas measurement. Due to quasi-TE and quasi-TM mode guiding characteristics in one-dimensional (1D) PCW, a novel slow-light-enhanced polarization division multiplexing infrared absorption spectroscopy was proposed for on-chip wideband multigas detection. The optimized 1D PCW gas sensor experimentally shows an impressive slow-light mode bandwidth exceeding 100 nm (TM, 1500–1550 nm; TE, 1610–1660 nm) with a group index ranging from 4 to 25 for the two polarizations. The achieved bandwidth in the 1D PCW is 2–3 times that of the reported quasi-TE polarized 2D PCWs. By targeting the absorption lines of different gas species, multigas detection can be realized by modulating the lasers and demodulating the absorption signals at different frequencies. As an example, we performed dual-gas measurements with the 1D PCW sensor operating in TE mode at 1.65 μm for methane (CH4) detection and in TM mode at 1.53 μm for acetylene (C2H2) detection. The 1 mm long sensor achieved a remarkable limit of detection (LoD) of 0.055% for CH4 with an averaging time of 17.6 s, while for C2H2, the LoD was 0.18%. This polarization multiplexing sensor shows great potential for on-chip gas measurement because of the slow-light enhancement in the light–gas interaction effect as well as the large slow-light bandwidth for multigas detection.