Thermodynamic and Dielectric Studies Concerning the Influence of Cylindrical Submicrometer Confinement on Heptyloxycyanobiphenyl

• Published in: The journal of physical chemistry. B Vol. 109; no. 49; pp. 23209 - 23217
• Main Authors: Diez, S, López, D. O, de la Fuente, M. R, Pérez-Jubindo, M. A, Salud, J, Tamarit, J. Ll
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 15-12-2005
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp054124f

Measurements of the specific heat and the static dielectric permittivity of heptyloxycyanobiphenyl (7OCB) confined to the 0.2 μm diameter parallel cylindrical pores of Anopore membranes in the isotropic phase and nematic mesophase, are presented. A comparison between the bulk and the confined 7OCB in treated and untreated pore wall surfaces using a chemical surfactant (HTBA) is performed. Both the treated and untreated membrane confinements seem to affect the nematic-to-isotropic phase transition by a downshift in transition temperature and some rounding at the specific-heat maximum, in a way similar to that which was earlier published for other liquid crystals confined in the same geometry. The static dielectric measurements clearly point out that untreated membrane confinement is axial, with the nematic director aligned parallel to the pore axis being homeotropic bulklike, i.e., with the nematic director aligned perpendicular to the electrode cell surfaces. After chemical surfactant treatment, the nematic director is constrained in a radial alignment being perpendicular to the pore walls. The dielectric measurements are revealed to be specially sensible to analyze the surface-induced nematic order due to the pore wall. The tricritical nature of the nematic-to-isotropic phase transition in bulk 7OCB as well as in treated and untreated Anopore confined geometries is discussed through both the specific heat and the static dielectric data.