Formation and Mechanical Characterization of Aminoplast Core/Shell Microcapsules
This work aims at establishing a link between process conditions and resulting micromechanical properties for aminoplast core/shell microcapsules. The investigated capsules were produced by the in situ polymerization of melamine formaldehyde resins, which represents a widely used and industrially re...
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| Published in: | ACS applied materials & interfaces Vol. 4; no. 6; pp. 2940 - 2948 |
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| Main Authors: | , , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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American Chemical Society
27-06-2012
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| Abstract | This work aims at establishing a link between process conditions and resulting micromechanical properties for aminoplast core/shell microcapsules. The investigated capsules were produced by the in situ polymerization of melamine formaldehyde resins, which represents a widely used and industrially relevant approach in the field of microencapsulation. Within our study, we present a quantitative morphological analysis of the capsules’ size and shell thickness. The diameter of the investigated capsules ranged from 10 to 50 μm and the shell thickness was found in a range between 50 and 200 nm. As key parameter for the control of the shell thickness, we identified the amount of amino resin per total surface area of the dispersed phase. Mechanical properties were investigated using small deformations on the order of the shell thickness by atomic force microscopy with a colloidal probe setup. The obtained capsule stiffness increased with an increasing shell thickness from 2 to 30 N/m and thus showed the same trend on the process parameters as the shell thickness. A simple analytical model was adopted to explain the relation between capsules’ geometry and mechanics and to estimate the elastic modulus of the shell about 1.7 GPa. Thus, this work provides strategies for a rational design of microcapsule mechanics. |
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| AbstractList | This work aims at establishing a link between process conditions and resulting micromechanical properties for aminoplast core/shell microcapsules. The investigated capsules were produced by the in situ polymerization of melamine formaldehyde resins, which represents a widely used and industrially relevant approach in the field of microencapsulation. Within our study, we present a quantitative morphological analysis of the capsules' size and shell thickness. The diameter of the investigated capsules ranged from 10 to 50 μm and the shell thickness was found in a range between 50 and 200 nm. As key parameter for the control of the shell thickness, we identified the amount of amino resin per total surface area of the dispersed phase. Mechanical properties were investigated using small deformations on the order of the shell thickness by atomic force microscopy with a colloidal probe setup. The obtained capsule stiffness increased with an increasing shell thickness from 2 to 30 N/m and thus showed the same trend on the process parameters as the shell thickness. A simple analytical model was adopted to explain the relation between capsules' geometry and mechanics and to estimate the elastic modulus of the shell about 1.7 GPa. Thus, this work provides strategies for a rational design of microcapsule mechanics. |
| Author | Berthier, Damien Ouali, Lahoussine Fery, Andreas Pretzl, Melanie Kunert, Carmen Kuttner, Christian Neubauer, Martin Leon, Géraldine Tekaat, Melanie Erni, Philipp |
| AuthorAffiliation | University of Bayreuth Firmenich SA |
| AuthorAffiliation_xml | – name: University of Bayreuth – name: Firmenich SA |
| Author_xml | – sequence: 1 givenname: Melanie surname: Pretzl fullname: Pretzl, Melanie – sequence: 2 givenname: Martin surname: Neubauer fullname: Neubauer, Martin – sequence: 3 givenname: Melanie surname: Tekaat fullname: Tekaat, Melanie – sequence: 4 givenname: Carmen surname: Kunert fullname: Kunert, Carmen – sequence: 5 givenname: Christian surname: Kuttner fullname: Kuttner, Christian – sequence: 6 givenname: Géraldine surname: Leon fullname: Leon, Géraldine – sequence: 7 givenname: Damien surname: Berthier fullname: Berthier, Damien – sequence: 8 givenname: Philipp surname: Erni fullname: Erni, Philipp – sequence: 9 givenname: Lahoussine surname: Ouali fullname: Ouali, Lahoussine – sequence: 10 givenname: Andreas surname: Fery fullname: Fery, Andreas email: andreas.fery@uni-bayreuth.de |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22583902$$D View this record in MEDLINE/PubMed |
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| Keywords | controlled release compression behavior emulsions melamine formaldehyde capsules hollow polymer shells stability elastic properties |
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