Thiadiazole-Derived Expanded Heteroazaporphyrinoids

Thiadiazole-Derived Expanded Heteroazaporphyrinoids

Heteroannulenes 1 and 3 containing three subunits of isoindole or pyrrole, respectively, three 1,3,4-thiadiazole moieties, and six aza-bridges have been synthesized by reaction of the corresponding diiminoisoindoline or diiminopyrroline with 2,5-diamino-1,3,4-thiadiazole. These conjugated nonaromati...

Full description

Saved in:
Bibliographic Details
Published in:Organic letters Vol. 3; no. 14; pp. 2153 - 2156
Main Authors: Islyaikin, Mikhail K, Danilova, Elena A, Yagodarova, Larisa D, Rodríguez-Morgade, M. Salomé, Torres, Tomás
Format: Journal Article
Language:English
Published: United States American Chemical Society 12-07-2001
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Heteroannulenes 1 and 3 containing three subunits of isoindole or pyrrole, respectively, three 1,3,4-thiadiazole moieties, and six aza-bridges have been synthesized by reaction of the corresponding diiminoisoindoline or diiminopyrroline with 2,5-diamino-1,3,4-thiadiazole. These conjugated nonaromatic 30 π-electron macrocycles coordinate three metal ions within their central cavity and constitute one of the rare examples of expanded heteroazaporphyrinoids.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol015924l