Diels−Alder Reaction between Indoles and Cyclohexadienes Photocatalyzed by π,π Aromatic Ketones

Diels−Alder Reaction between Indoles and Cyclohexadienes Photocatalyzed by π,π Aromatic Ketones

Diels−Alder reactions between indoles and cyclohexadienes can be photocatalyzed by benzoylthiophenes. Both experimental and theoretical studies show that the reactions occur through ternary excited triplet state complexes (triplet triplexes).

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Bibliographic Details
Published in:Organic letters Vol. 6; no. 22; pp. 3905 - 3908
Main Authors: Pérez-Prieto, Julia, Stiriba, Salah-Eddine, González-Béjar, María, Domingo, Luis R, Miranda, Miguel A
Format: Journal Article
Language:English
Published: United States American Chemical Society 28-10-2004
Online Access:Get full text
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Description
Summary:Diels−Alder reactions between indoles and cyclohexadienes can be photocatalyzed by benzoylthiophenes. Both experimental and theoretical studies show that the reactions occur through ternary excited triplet state complexes (triplet triplexes).
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol048520c