Synthesis, Structure, and Fluxionality of (μ-Diphenylsilylene)(fulvalene)tetracarbonyldirhenium Double Si−H Activation to the First Fulvalene Silylene Complex

Synthesis, Structure, and Fluxionality of (μ-Diphenylsilylene)(fulvalene)tetracarbonyldirhenium Double Si−H Activation to the First Fulvalene Silylene Complex

(Fulvalene)hexacarbonyldirhenium (1) furnishes the first silylene fulvalenedimetal complex 3 by double Si−H activation. The solid-state structure of the molecule was determined by X-ray analysis and its solution dynamics by 1H NMR spectroscopy.

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Bibliographic Details
Published in:Organometallics Vol. 19; no. 12; pp. 2389 - 2392
Main Authors: Kayser, Bernd, Eichberg, Michael J, Vollhardt, K. Peter C
Format: Journal Article
Language:English
Published: American Chemical Society 12-06-2000
Online Access:Get full text
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Summary:(Fulvalene)hexacarbonyldirhenium (1) furnishes the first silylene fulvalenedimetal complex 3 by double Si−H activation. The solid-state structure of the molecule was determined by X-ray analysis and its solution dynamics by 1H NMR spectroscopy.
Bibliography:ark:/67375/TPS-MJ4JZWGL-P
istex:8B7D6FB0D93E82088808E57FE5971121A2ED907C
ISSN:0276-7333
1520-6041
DOI:10.1021/om000022u