Purcell Factor for Plasmon-Enhanced Metal Photoluminescence

• Published in: Journal of physical chemistry. C Vol. 127; no. 12; pp. 5898 - 5903
• Main Author: Shahbazyan, Tigran V.
• Format: Journal Article
• Language: English
• Published: American Chemical Society 30-03-2023
• Subjects: C: Spectroscopy and Dynamics of Nano, Hybrid, and Low-Dimensional Materials
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/acs.jpcc.3c00180

We present an analytical model for the plasmonic enhancement of metal photoluminescence (MPL) in metal nanostructures with a characteristic size below the diffraction limit. In such systems, the primary mechanism of MPL enhancement is the excitation of localized surface plasmons (LSP) by recombining carriers, followed by photon emission due to LSP radiative decay. For plasmonic nanostructures of arbitrary shape, we obtain a universal expression for the MPL Purcell factor that describes the plasmonic enhancement of MPL in terms of the metal dielectric function, LSP frequency, and system volume. We find that the lineshape of the MPL spectrum is affected by the interference between direct carrier recombination processes and those mediated by plasmonic antenna, which leads to a blueshift of the MPL spectral band relative to LSP resonance in scattering spectra observed in numerous experiments.