Structure and Electronic Properties of a Continuous Random Network Model of an Amorphous Zeolitic Imidazolate Framework (a-ZIF)

• Published in: Journal of physical chemistry. C Vol. 120; no. 28; pp. 15362 - 15368
• Main Authors: Adhikari, Puja, Xiong, Mo, Li, Neng, Zhao, Xiujian, Rulis, Paul, Ching, Wai-Yim
• Format: Journal Article
• Language: English
• Published: American Chemical Society 21-07-2016
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/acs.jpcc.6b06337

Zeolitic imidazolate frameworks (ZIFs) are a rapidly emerging class of versatile porous material with many potential applications. Here, we report the construction of an amorphous ZIF (a-ZIF) model from a near-perfect continuous random network model of a-SiO2. The radial distribution function is in good agreement with measurements for amorphous aTZIF-4 but with notable fine differences. The electronic structure and properties of the a-ZIF model are critically compared with those of three crystalline ZIF phases, ZIF-4, ZIF-zni, and ZIF-8, using density functional theory methods. We confirm the retention of the metal tetrahedral bonding coordination in a-ZIF and the nearly identical short-range ordering found in crystalline ZIFs. The considerable Zn–N bond strength plays a key role in retaining the tetrahedrally bonded network structure. The calculated optical properties of a-ZIF show a complex absorption spectrum with an ultralow refractive index n of 1.327 and a plasmon frequency of 15.810 eV.