A study of polyhedral cage fluxionality in carboranes. Solution and solid-state structures of R4C4B8H8 isomers

A study of polyhedral cage fluxionality in carboranes. Solution and solid-state structures of R4C4B8H8 isomers

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 106; no. 21; pp. 6187 - 6193
Main Authors: Venable, T. Leon, Maynard, Richard B, Grimes, Russell N
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 01-10-1984
Subjects:
Atomic and molecular physics
Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)
Exact sciences and technology
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Chemical solution
Cage compound
Steric effect
Fluxional behavior
Carborane
Experimental study
NMR spectrum
X ray diffraction
Organic compounds
Conformation
Crystalline structure
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Description
Bibliography:ark:/67375/TPS-06XVSWMV-2
istex:D11A324D93D341AB74BF9A96BBFDD39569E1D7FB
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00333a011