Ligand replacement at a square planar metal center: A kinetic experiment for the inorganic chemistry laboratory

The ligand triphenyl phosphine is replaced from a rhodium metal center by a series of pyridine derivatives; this system will introduce students to stopped-flow spectrophotometry as a technique to study the kinetics of very fast reactions.

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Bibliographic Details
Published in:	Journal of chemical education Vol. 64; no. 3; p. 262
Main Authors:	Kruger, H, de Waal, D. J. A
Format:	Journal Article
Language:	English
Published:	Division of Chemical Education 01-03-1987
Subjects:	Second-Year Undergraduate Hands-On Learning / Manipulatives Coordination Compounds Inorganic Chemistry
Online Access:	Get full text
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Description
Summary:	The ligand triphenyl phosphine is replaced from a rhodium metal center by a series of pyridine derivatives; this system will introduce students to stopped-flow spectrophotometry as a technique to study the kinetics of very fast reactions.
ISSN:	0021-9584 1938-1328
DOI:	10.1021/ed064p262