Utilization of CO2 as a C1 Building Block for Catalytic Methylation Reactions

Utilization of CO2 as a C1 Building Block for Catalytic Methylation Reactions

Developing new synthetic approaches for benign CO2 utilization is of current interest. In this respect, reductive alkylations using N- or C-based nucleophiles to give the corresponding methyl amines and (hetero)­arenes are investigated intensively. Crucial points for such benign methylations are the...

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Bibliographic Details
Published in:ACS catalysis Vol. 7; no. 2; pp. 1077 - 1086
Main Authors: Li, Yuehui, Cui, Xinjiang, Dong, Kaiwu, Junge, Kathrin, Beller, Matthias
Format: Journal Article
Language:English
Published: American Chemical Society 03-02-2017
Subjects:
amines
carbon dioxide
catalysis
reduction
methylation
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Summary:Developing new synthetic approaches for benign CO2 utilization is of current interest. In this respect, reductive alkylations using N- or C-based nucleophiles to give the corresponding methyl amines and (hetero)­arenes are investigated intensively. Crucial points for such benign methylations are the choice of suitable homogeneous or heterogeneous catalyst systems. In this article, selective activation of the substrates and the use of acidic cocatalysts are highlighted.
ISSN:2155-5435
2155-5435
DOI:10.1021/acscatal.6b02715