Apparent concurrent acetylene-vinylidenecarbene rearrangements, silyl-acetylide metathesis, and alkyne cleavage in the interaction of bis(trimethylsilyl)acetylene with (.eta.5-C5H5)Co(CO)2. Crystal and molecular structure of a novel biscarbyne complex: [.mu.3.eta.1-CSi(CH3)3][.mu.3.eta.1-C3Si(CH3)3][(.eta.5-C5H5)Co]3

Apparent concurrent acetylene-vinylidenecarbene rearrangements, silyl-acetylide metathesis, and alkyne cleavage in the interaction of bis(trimethylsilyl)acetylene with (.eta.5-C5H5)Co(CO)2. Crystal and molecular structure of a novel biscarbyne complex: [.mu.3.eta.1-CSi(CH3)3][.mu.3.eta.1-C3Si(CH3)3][(.eta.5-C5H5)Co]3

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 101; no. 10; pp. 2768 - 2770
Main Authors: Fritch, John R, Vollhardt, K. Peter C, Thompson, Michael R, Day, Victor W
Format: Journal Article
Language:English
Published: American Chemical Society 01-05-1979
Online Access:Get full text
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Description
Bibliography:ark:/67375/TPS-DN7WQGQT-2
istex:BE7FC8A7224FDFA55CD8E69CA2F15BBB4B5921FF
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00504a065